![]() Method and installation for straightening metallic parts
专利摘要:
The invention relates to a method and a device for the straightening of a metallic straightening object (1), wherein the system comprises a data processing system and a straightening device (2), wherein the straightening device (2) comprises a frame (3), holders (4) for holding of the straightening object (1), sensors for measuring the geometry of the straightening object (1), and straightening punches (6) for force-induced changing the shape of the straightening object (1), wherein the data processing system with the sensors and the straightening dies (6) in combination is, and is able to control movement of the straightening stamp (6), characterized in that the data processing system comprises a database (7) in which data regarding starting situation, measures and results of already occurring deformation processes are included in guide objects (1) and in which data are incurred during operational straightening, are automatically fed. 公开号:AT516761A4 申请号:T300/2015 申请日:2015-05-13 公开日:2016-08-15 发明作者:Josef Gebeshuber 申请人:Gtech Automatisierungstechnik Gmbh; IPC主号:
专利说明:
ALR description The invention relates to a method and a system for the straightening of metallic parts. After prototyping, typically after casting, the shape of metallic parts often deviates somewhat from the desired final shape. The "straightening" is a process step in which a urgeformter part depending on observed dimensional differences to the .Sollmaßen plastically deformed until ideally all dimensions correspond to the nominal dimensions. The application of the invention is particularly advantageous when the geometry of the metallic parts consists mainly of flat sections that are complex curved and / or composed of differently oriented sections, so that the exact prediction of plastic deformation by bending force by means of hydraulic stamping or Similar, not or only with many difficulties and restrictions is possible. Such parts are, for example, rather larger, flat aluminum die castings of complex shape, which have a statically supporting function as part of the chassis of an automobile. DE 196 11 897 C2 deals with the straightening of elongated; metallic parts. A part is first measured and then straightened by bending. The plastic bending deformation due to the deformation path temporarily forced by the bending tool is calculated taking into account the material properties. j The movement of the bending tool in the bending operation is composed of a large, equal movement and a movement of this superimposed, rapid sequence of forward-backward movements with a relatively small stroke. To calculate the bending result, numerical values representing material parameters are stored in the calculation program. In adaptation to MR The results of actual straightening operations can be used to change these stored numerical values, so that with increased empirical values, the calculation is increasingly better aligned with reality. The method is very well suited for simple elongated parts in which only a few different form deviations are to be corrected in practice. For the straightening of parts with more complex geometry, the method is not applicable due to the drastically increasing computing complexity with the complexity. In DE 102004043401 Al it is proposed to direct aluminum castings by means of an embossing tool. The embossing tool has several pairs, each consisting of the lower part and upper part, on, wherein all pairs together include a mold cavity, and wherein pairs can be arranged individually offset relative to the other pairs in the closing direction of the embossing tool. By subsequent embossing of the cast workpiece in this tool, the workpiece is plastically deformed. By setting the offset of the individual pairs of lower and upper parts against each other, systematic geometric errors of the castings can be well corrected. Due to the high cost of producing and optimizing the shape of the method is only economically useful if large series are manufactured and thereby the deviations from part to part are always pretty much the same after casting. DE 102008003882 B4 deals with an advantageous method for straightening flat metal castings, in particular aircraft window frames. After solution heat treatment; automatically measure the geometry of the casting and automatically calculate the amount of deformation required at each surface area, with the amount of displacement of surface areas normal to its plane being important. The directional deformation is then performed by blasting a blasting stock as typically i Steel balls normal to their surface on selected area ALR rich is radiated. The straightening can be iteratively operated in several cycles of measuring and blasting to the desired end result. Above all, its flexibility is advantageous in the method. It can be automated so far / that it automatically responds to part deviations in shape during series production. For the production in larger series .ist is disadvantageous that the cycle time is relatively long. Due to the forming by a blasting medium and the maintenance and equipment costs for the system is relatively high. The object of the invention is to provide a method for straightening a straightening object, wherein the straightening object may be a urgeformtes metal part, in particular a metal casting. In contrast to the methods known from the prior art discussed, the method to be created should be advantageous with respect to all of the following criteria: a) Applicability even with very complex geometry of the directive object. b) Automatic selection of the respectively appropriate straightening, even if the deviation from straightening object to straightening object is very different. c) Short cycle time d Little effort for maintenance and equipment of the plant. For solving the problem, a method is assumed which proceeds as follows: The straightening object is kept defined and the geometry that the straightening object has when it is in a relaxed state is detected metrologically. Then it is calculated in which direction and by what amount geometric dimensions of the straightening object deviate from the stored nominal dimensions. Then the straightening object is subjected to a repetitive sequence of work steps if necessary, comprising the following working steps: ALR - Selection of a deformation to be applied to the straightening object by one or more straightening punches. - Perform the selected deformation. - Canceling the action of the directional stamp on the rectal object. "Direct or indirect metrological detection of the geometry that has the straightened object in a relaxed state. - Calculate in which direction and by what amount geometric dimensions of the straightening object deviate from the stored nominal dimensions. j The procedure is over when either in the latter Work step no deviations from the target dimensions are more Fest- I made, or if another Abforuchbedingung reached: is. 1 As an improvement according to the invention to this known per se The following two measures are provided by way of procedure: i - the selection to be made in the first step ("selection of a deformation which is to be applied to the directional object by one or more aiming punches") is made using a database of a database; which data contains the initial situation, measures and results of already occurring deformation processes on directive objects. j - data concerning the deformation processes performed at the currently directed straightening object (respective initial geometry, Measures, result geometry) are fed into the database and the said dataset about past deformation processes is thereby extended. ALR By the measures according to the invention, which are actually surprisingly easy to implement even in existing systems, a self-learning system is created, which continuously exploits the experience gained in concrete straightening and perfecting of straightening object to straightening judging and gradually for rare occurring combinations of dimensional deviations reliably delivers successful straightening recipes. Fig. 1: shows extremely stylized essential mechanical compo nents of a directional device used in the invention Fig. 2: shows the basic flow scheme according to wel chem according to the method according to the invention a straightening object is directed. According to Fig. 1, the straightening object 1 in a straightening device 2! arranged. The straightening device 2 has a rigid frame 3. Brackets 4 protrude from the frame 3 onto defined points of the straightening object 1 and fix these points of the straightening object 1 relative to the frame 3. Typically, three brackets 4 are used. A holder 4 may for example be formed by two hydraulic or pneumatic cylinders, which are directed from the frame 3 from opposite sides to the straightening object 1 and whose position is optionally mechanically lockable. On the frame 3, according to the example outlined, a row of measuring sensors 5 is arranged, which project at the straightening object 1 and measure the distance of the surface of the straightening object 1 from the frame 3 at a plurality of points. The sketched measuring sensors 5 can be, for example, controlled telescopically extendable bars, at the free tip of which there is a touch or pressure sensor which generates a signal when it is connected with the Directive object comes into contact. The necessary distance measurement between points of the frame 3 and points of the directional object. 1 However, ALR could also be carried out without contact by means of optical methods. From the frame 3 further protrudes a plurality of Richtstempeln 6 on the straightening object 1. The straightening are typically hydraulic cylinder whose stroke can be controlled and measured and of which ideally also the force can be controlled or at least measured, Of course, another drive principle than Hydraulic for driving the straightening imaginable, for example, electrically (eg with motor-driven screw spindle) or pneumatically. The procedure is illustrated briefly with reference to the drawings: Step a (FIG. 2): The straightening object 1 is inserted into the straightening device 2 in a defined position and orientation. The brackets 4 are closed and the straightening object relative to the frame 3 in a defined position rigid | and de facto kept tension-free. In detail, work step a can proceed as follows: The straightening object 1 is first placed on storage points that protrude from the frame 3 upwards. Then drive from below three brackets 4 as far as each one of three reference points on the rectilinear object 1, that this rests with the three reference points on the three brackets 4 in a three-point support. Then drive exactly from the opposite side (ie from above) forth three more brackets 4 to the object. close and keep this also upwards backlash-free, but doing it as well as possible without force and thus as good as possible tension-free. Step b: With the aid of the measuring sensors 5, which measure distances, their position relative to the frame 3 is measured for a number of points on the surface of the straightening object 1. ALR Step c: A - not shown - Datenverarbei investment facility calculates the differences between measured position data of surface points of the target object 1 to ideal position data of these surface points and thus how much the surface of the target object 1 is displaced at these surface areas over the ideal position. According to an advantageous - because simple but still effective - procedure of the displacement of the individual surface points compared to the ideal position only that scalar value is measured and recorded, which states how much the considered surface point in the normal direction to the surface under consideration compared to the ideal position is. The data record which describes how much the individual measured surface points of the directional object 1 are shifted relative to their ideal position is referred to as a "displacement data set". Mathematically, it can be viewed and treated in much the same way as a vector. This data record is read into a database 7. Step d: The data processing system checks whether the measured values of shifts are within the respective permissible limits or not. If every value of the displacement data set is within the permitted limits, the object is at the target. 1 no further straightening required. If values lie outside of said limits, it is decided on the basis of deposited criteria whether a straightening process is carried out, or whether the straightening object is defined as scrap and eliminated from further processing. Elimination may be required, for example, if dimensional deviations are so great that the necessary deformability of the material is not sufficient to be able to correct this by straightening, or if the straightening object has already been approved. ALR has reached the maximum number of straightening cycles. If it is determined that straightening is required, proceed to step e. Step e: By comparing the in step, c festgest th displacement data set with stored in the database 7 displacement data sets, which also data on judging processes are deposited, a record is set, which states how the individual alignment punches 6 are to move. This record is further referred to as a "motion record". Exemplary advantageous algorithms which lead to the advantageous definition of the movement data record are described in detail below. In the database 7 it is noted which movement data record was selected. Step f: The, according to set in step e Movement record affected straightening 6, are moved to the starting position on the object 1 and. the movements according to the movement data record are carried out. In general, it is sufficient to start the movements of the individual alignment punches 6 to be performed in accordance with the movement data record all at the same time and run them to their respective end j. In the case of very complex geometries and deformations, however, it may also be expedient to define a detailed chronological sequence of movements of the alignment punches 6. Step g: The straightening 6 are relaxed and possibly all something back from the straightening object 1, so that the straightening object can take its relaxed form. Eventually one or two brackets 4 will be loosened. Step b (second pass): see above text for "Work step b". ALR Work step c (second pass): see above text for "Work step c". Supplement: In addition to the calculation which yields a new displacement data set as a result, it is now also calculated how the shape of the directional object has changed from the state before the leveling cycle. The data record describing this change is further referred to as a "modification data set" , It is stored in the database 7 and is there associated with the last applied motion data set, which has led to the relevant changes to the target object 1. The change data record can be formed simply by those numerical values which describe by how much the values measured by the individual measuring sensors 5 on the same directional object 1 differ before and after the straightening process (step f). Mathematically, the change data set can also be viewed and treated in much the same way as a vector. The described cycle is run through until it is either determined in step d that the geometry of the directional object corresponds to the desired geometry or until another abort criterion is met. In the database 7, the mentioned data records displacement data record, movement data record and change data record are best stored in each case in the form of a combination of a vector and an amount. The vector is an ordered group of several numerical values and the amount is a simple scalar number. Using the example of the displacement data set, the deviations from the ideal position of the respective surface areas of the straightening object 1 recorded at the individual measuring sensors 5 are recorded in the vector, but not in a numerical value which is ih ÄLR rer absolute size, but in a normalized size, so that the vector is a kind of unit vector. Only by multiplying the numerical values of the individual components of the vector by the amount, one arrives at those numerical values which state the distance by which the respective individual sensor 5 displaces the local surface area of the rectilinear object 1 from the ideal position. Analogous to the usual method in the vector calculation, the amount can be calculated as the root of the sum of the squares of the individual values of the j measured at the individual probes 5 shifts. The individual components of said (unit) Vectors are then the individual displacement values, dividing j by the magnitude. On the motion data set, the individual components of the (single-belt) vector are each assigned to a specific alignment punch 6. Analogously to the displacement data record, the amount by which a straightening pad 6 must be moved during a straightening process results from the multiplication of the component of the vector associated with the straightening stamp with the amount. ( In the case of the change data record, as with the displacement data record, the individual components of the vector are assigned to the individual measuring sensors 5 'and thus to the surface areas of the directional object 1 whose position is detected by measuring sensors 5. The components of the vector associated with the change data set multiplied by the amount associated with the change record yield the respective distance by which a surface area has been shifted, according to the heading data corresponding to that motion data set associated with the change record. There are probably an infinite variety of algorithms, according to which, by a data processing system, the database 7 can be operated and motion data sets can be set. ALR Assuming that displacement records, motion records, and change records are stored as described as a combination of unit vector and scalar, a simple and efficient algorithm for selecting a motion record (step e of FIG. 2) may function as follows: For the displacement data set of the currently available directional object, the most suitable change data set must be selected from the change data sets stored in the database 7. The vector contained in the displacement data set has approximately the meaning of a direction, as do the vectors contained in the change data sets. It simply searches for that change data set whose vector belongs to the vector of the j Sliding data set is directed as accurately as possible against. Gen; According to the known rules of vector calculation, that vector is that vector in which the inner product, with the vector of the displacement data set, has the largest negative numerical value. Has. Consequently, by the data processing system, the inner product of the vector of the displacement data set is formed of the vectors of all the change data sets, and that change data set is selected in which the result - ie the inner product - has the largest negative numerical value. (The inner product of two vectors is obtained as the sum of the products of the numerical values of the similar components; 2.B .:; (a / b). (C / d) - a.c + b.d) In the next step, the amount of the current displacement data set is multiplied by the absolute value of the previously found inner product (which has the largest negative value), and divided by the amount of the change data set found. The result multiplies the amount of motion data set associated with the change record in the database 7. ALR This results in a newly formed movement data record. Applying this as the law of motion for the alignment punches 6 (step f of FIG. 2) theoretically results in a change data set which is the same as the previously selected change data set and which is large enough to match the present displacement at the change data set given Change direction corrected as best as possible. It is already possible to apply the calculated movement data set immediately and thus to proceed further in the cycle according to FIG. 2. If one already sees in the precalculation in step e that I calculate the calculated motion data set Although an improved offset data set will result from this table, but this will still not be within the target range (because the predicted change does not go in exactly the right direction), it is recommended that the determination of the motion data set to be used beforehand Refine. Only for the calculation can one suppose that the first found motion data set was applied, that the theoretically predicted further displacement data set was obtained and for this further displacement data set, as described again a further change data set, besides belonging, as described suitably scaled further movement data set: calculate. The actual motion data set is then the vectorial addition of the first calculated motion data set with the subsequently calculated motion data set. ! Theoretically, one could predict and superimpose more than two motion data sets. It is important that the information about the ultimately applied motion data sets including the associated information, ie original displacement data; set and achieved change data set in the database 7 i AIR, so that it improves the database and teaches the system. It is. makes sense to set limiting boundary conditions for deformations and automatically monitor, with the relevant limits resulting from the properties of the material of the object 1. For example, there should be an upper limit for the entire deformation path and also an upper limit for the number of deformation processes. It makes sense in the movement through which Richtstempel 6 the j Deformation object .1 deform to distinguish whether the movement elastic! see or plastic deformation of the directional object causes. At least approximately, one can recognize the transition from elastic deformation to plastic deformation, as is known, on the basis of the flatness of the functional graph, which describes the deformation force as a function of the deformation path. It therefore makes sense, at the Richtstempeln 6, both way and force constantly mitzumessen and in the data processing system with respect Ver! evaluate the shaping effect. For the data stored in the movement data records, the movements of the alignment punches 6 which perform these while plastically deforming them on the target object 1 are of crucial importance. In an advantageous embodiment of a device according to the invention, the straightening punches 6 are also equipped with a sensor by means of which they can detect contact with the straightening object 1, so that they can also perform the function of measuring sensors 5. In an advantageous embodiment, the straightening 6 can also take over the function of brackets 4, so hold points of the straightening object 1 to which they rest in a relation to the frame 3 rigid position. AIR In an advantageous embodiment, the straightening punches 6 are mounted on a different frame than the measuring probes 5 and the frame which carries the measuring probes 5 is held independently of the frame which carries the straightening punches 6. In this way, those measurement errors are easily avoided, which otherwise arise from the fact that the frame, which carries the straightening, in the force application by the straightening punches on the straightening object, forcibly even something is deformed. Of course, it is very useful if there is a user interface to the data processing system, which controls the straightening device 2 and includes the database 7. Ideally, this user interface can be used to view data about current work processes, edit stored data, and influence the selection of movements of rule marks 6 (step e). In particular, during the learning phase of a system according to the invention, it is useful if in step e motion data sets can be easily specified and entered by people. It is advantageous with respect to data records stored in the database 7 to carry out statistical evaluations and to assign evaluative classifications derived therefrom to the individual data records. For example, it can be seen that some motion data sets perform better reproducibly to predeterminable change data sets than others, and that some motion data sets disturbing often result in damage to a Richtobjekt.es. By statistical analysis - which can be done by the data processing system also automatically - thus prohibition rules for problematic motion data sets can be automatically generated and brought to automatic application. Likewise, a group of particularly well-functioning agitation data sets can thus be identified and selected from them as preferred.
权利要求:
Claims (3) [1] 1. A method for straightening a metallic straightening object (1) wherein the straightening object (1) is held in a defined position relative to the frame (3) of a straightening device (2), the geometry of the straightening object (1) is detected metrologically, is calculated in which direction and by what amount the position of individual surface areas of the straightening object deviates from a stored ideal position, and the straightening object of a repetitive sequence of working steps - calculate in which direction and by what amount geometric dimensions of the straightening object deviate from the stored nominal dimensions, - selection a deformation which is applied by one or more straightening punches (6) on the straightening object (1). - Perform the selected deformation, - Cancel the force of the straightening punches (6) on the straightening object (1), - Measure the geometry of the straightening object (l) and calculate in which direction and by what amount the position of individual surface areas of the straightening object of a deposited ideal position is subject to, is characterized in that the selection of a deformation is made using that database of a database (7), which includes data on the starting situation, measures and results of already occurring deformations on directive objects, and ALR that data during operational straightening processes are automatically fed into the database (7) and expand the database for further selections of deformations on directive objects (1). [2] 2. The method according to claim 1, characterized in that the data contain a displacement data set, a movement data set and a change data record, wherein the displacement data set contains statements about the deviation of the shape of the directional object (1) from the ideal shape, the motion data set contains statements about movements of the alignment punches (6) j with which they deform the straightening object (1) and the modification data record contains statements as to how the shape of the straightening object (1) was changed as a result of movement of the straightening stamps (6) according to {the motion data set. [3] 3. System for the straightening of a metallic straightening object (1), i whereby the system has a data processing system and a straightening device (2), wherein the straightening device (2) comprises a frame (3), holders (4) for holding the straightening jj jektes (1), sensors for the measurement of the geometry of the Rieht object (1), as well as directional stamp (6) for the force-induced changing the shape of the directional object (1), wherein the data processing system with the sensors and the Richtstem- jeln in Connection is, and is able to control movement of the directional stamp (6), j characterized in that the data processing system comprises a database (7) in which data regarding starting situation, measures and results of already occurring deformation operations on directive objects (1) included are and in which data are incurred during operational straightening, are automatically fed.
类似技术:
公开号 | 公开日 | 专利标题 AT401484B|1996-09-25|METHOD AND DEVICE FOR SETTING A BENDING PROCESS AND METHOD FOR PREPARING BENDING DATA DE102011050001A1|2012-10-31|Method and device for producing flangeless drawn parts EP1173299A1|2002-01-23|Automated method and device for the non-cutting shaping of a body WO2015019285A1|2015-02-12|Bending press DE102014106289A1|2015-11-12|Method and plant for machining a metallic casting AT516761B1|2016-08-15|Method and installation for straightening metallic parts DE1935080A1|1970-12-17|Method of automatic production of sipes for tire molds and automatic sipe-making machine DE102015002280B4|2019-10-17|Method and installation for automated straightening of a casting DE2346797A1|1975-04-03|AUTOMATIC STRAIGHTING PROCEDURE AND STRAIGHTING PRESS WITH ONE STRAIGHTING OFFICE EP2177291B1|2015-04-15|Method for cutting and/or forming of workpieces DE102012011893B4|2014-11-20|Method and device for spotting a tool in a press EP3274110B1|2019-01-09|Forming tool and method for optimizing board forming in a forming tool EP2839894B1|2015-11-04|Machine and method for the treatment of cast components WO2015198294A1|2015-12-30|Method for producing a bent part, and device for producing a bent part using a bending press or press brake and using a robot DE10000859A1|2000-10-26|Automatic process for reshaping a thin side wall of a component involves measuring deviations between actual and set geometries and using to locally heating areas to be reshaped under pressure DE102013006798A1|2014-03-20|Pressing tool for use in pressing line for processing metal sheet, has upper and lower tools enclosing cavity for processing workpiece, and processing robot arranged in cavity for processing workpiece in addition to processing by tools DE102013110855A1|2015-04-02|Forming device for incremental sheet metal forming DE813796C|1951-09-17|Method for calibrating forged bodies consisting of one or more pieces EP1641576A1|2006-04-05|Method for influencing a bending process DE102015016961A1|2016-06-09|Method and device for heating sheets and motor vehicle DE102004038209B4|2008-11-13|Tooling and method of forming EP3627258A1|2020-03-25|Motion planning for a servo press DE102018126336B4|2021-09-16|Method for controlling a bending machine, control for controlling a bending machine and bending machine EP0781611B1|1998-12-23|Process for the production of components from bar material, in particular stabiliser bars for motor vehicles DE102015122507A1|2017-06-22|Method and device for producing a rear axle carrier for a motor vehicle
同族专利:
公开号 | 公开日 PT3095533T|2020-05-22| AT516761B1|2016-08-15| ES2790728T3|2020-10-29| EP3095533A1|2016-11-23| HUE049266T2|2020-09-28| EP3095533B1|2020-02-26| PL3095533T3|2020-09-07| SI3095533T1|2020-07-31|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 DE19810140A1|1998-03-09|1999-09-30|Gerhard Koester|Measuring two wheel frame especially motor cycle frame e.g. after accident| EP1038602A1|1999-03-26|2000-09-27|SMS Demag AG|Method and device for straightening profiles| DE102007002320A1|2007-01-16|2008-09-04|Volkswagen Ag|Method for adjusting form of sheet metal part or component, involves preparing sheet metal part or component and inserting in leveling device, and measuring sheet metal part or component determining measured value| DE102011004167A1|2011-02-15|2012-08-16|Institut Dr. Foerster Gmbh & Co. Kg|Method and device for automated straightening of elongated material| DE102014106289A1|2014-05-06|2015-11-12|Bayerische Motoren Werke Aktiengesellschaft|Method and plant for machining a metallic casting| DE19611897C2|1996-03-26|2000-07-13|Imt Ind Mestechnik Gmbh & Co K|Process for bending, straightening and adjusting a metallic workpiece, in particular a hardened workpiece| DE10260909A1|2002-12-20|2004-07-01|Volkswagen Ag|Measurement and correction station for motor vehicle doors comprises numbers of measurement and correction devices together so that door defects can be individually corrected| DE102004043401A1|2004-09-08|2006-03-09|Volkswagen Ag|Casting component aligning method for use during manufacturing of cup-shaped mould, involves adjusting segments of embossing die along height of die based on azimuth of component, where component is aligned after heat treatment| DE102008003882B4|2008-01-10|2011-12-15|Otto Fuchs Kg|Method for producing an article made of metal, in particular from a high-strength aluminum alloy, and method for straightening such an article|DE102019117951B4|2019-07-03|2021-11-18|Automationsrobotic Gmbh|Method and robot system for reshaping, in particular corrective reshaping and / or straightening, of parts| DE102020118244A1|2020-07-10|2022-01-13|Laubinger + Rickmann GmbH & Co. KG|Device for correcting shape deviations of a structural component from a target geometry|
法律状态:
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 ATA300/2015A|AT516761B1|2015-05-13|2015-05-13|Method and installation for straightening metallic parts|ATA300/2015A| AT516761B1|2015-05-13|2015-05-13|Method and installation for straightening metallic parts| ES16001047T| ES2790728T3|2015-05-13|2016-05-10|Procedure for straightening metal parts| HUE16001047A| HUE049266T2|2015-05-13|2016-05-10|Method for straightening metallic parts| EP16001047.6A| EP3095533B1|2015-05-13|2016-05-10|Method for straightening metallic parts| PL16001047T| PL3095533T3|2015-05-13|2016-05-10|Method for straightening metallic parts| SI201630782T| SI3095533T1|2015-05-13|2016-05-10|Method for straightening metallic parts| PT160010476T| PT3095533T|2015-05-13|2016-05-10|Method and assembly for straightening metallic parts| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|